It is a remarkable fact that the second law of thermodynamics has played in the history of science a fundamental role far beyond its original scope. Suffice it to mention Boltzmann's work on kinetic theory, Planck's discovery of quantum theory or Einstein's theory of spontaneous emission, which were all based on the second law of thermodynamics.
Ilya PrigogineIn far from equilibrium conditions, the concept of probability that underlies Boltzmann's order principle is no longer valid if the structures we observe do not correspond to a maximum of complexions
Ilya PrigogineNow we see evolutionary trends in a variety of areas ranging from atomic and molecular physics through fluid mechanics, chemistry and biology to large scale systems of relevance in environmental and economic sciences
Ilya Prigogine