A hypothetical theory is necessary, as a preliminary step, to reduce the expression of the phenomena to simplicity and order before it is possible to make any progress in framing an abstractive theory.

The laws of thermodynamics may be regarded as particular cases of more general laws, applicable to all such states of matter as constitute Energy , or the capacity to perform work, which more general laws form the basis of the science of energetics, a science comprehending, as special branches, the theories of motion, heat, light , electricity , and all other physical phenomena.

In thermodynamics as well as in other branches of molecular physics , the laws of phenomena have to a certain extent been anticipated, and their investigation facilitated, by the aid of hypotheses as to occult molecular structures and motions with which such phenomena are assumed to be connected. The hypothesis which has answered that purpose in the case of thermodynamics, is called that of "molecular vortices," or otherwise, the "centrifugal theory of elasticity.

The hypothesis of molecular vortices is defined to be that which assumes - that each atom of matter consists of a nucleus or central point enveloped by an elastic atmosphere, which is retained in its position by attractive forces, and that the elasticity due to heat arises from the centrifugal force of those atmospheres revolving or oscillating about their nuclei or central points.According to this hypothesis, quantity of heat is the vis viva of the molecular revolutions or oscillations.

This law (regarding the theoretical efficiency of heat engines by Mr. Joule), and the law of the maximum efficiency of heat engines, are particular cases of a general law which regulates all transformation of energy, and is the basis of the Science of Energetics.

A hypothetical theory is necessary, as a preliminary step, to reduce the expression of the phenomena to simplicity and order before it is possible to make any progress in framing an abstractive theory.

It is possible to express the laws of thermodynamics in the form of independent principles , deduced by induction from the facts of observation and experiment, without reference to any hypothesis as to the occult molecular operations with which the sensible phenomena may be conceived to be connected; and that course will be followed in the body of the present treatise. But, in giving a brief historical sketch of the progress of thermodynamics, the progress of the hypothesis of thermic molecular motions cannot be wholly separated from that of the purely inductive theory.