One day I discovered that one could get the barrier to internal rotation in ethane approximately right using this method. This was the beginning of my work on organic molecules.
Roald HoffmannAlan Rocke's Image and Reality does so many things vividly and convincingly: it shows how visual images led chemistry step by step to the reality of the microscopic world; how simple portrayals of the logic of substitution and combination were reified; brings to our attention the imaginative, neglected work of Williamson and Kopp; and takes a critical look at Kekule's daydream. And it beautifully delineates the essential place the imagination has in science. A rewarding, lively picture of chemistry in formation.
Roald Hoffmann