Once you have your character sitting right there in your head, all you really need to do is wind them up, put them down, and simply write down what they do, say, or think.
Terry PratchettRincewind could scream for mercy in nineteen languages, and just scream in another forty-four.
Terry PratchettPeople were stupid, sometimes. They thought the Library was a dangerous place because of all the magical books, which was true enough, but what made it really one of the most dangerous places there could ever be was the simple fact that it was a library.
Terry PratchettI'm trying to have a moment o' existential dreed here, right? Crivens, it's a puir lookout if a man canna feel the chilly winds o' fate lashing aroound his netheres wi'out folks telling him he's deid, eh?
Terry PratchettWriting, for me, is a little like wood carving. You find the lump of tree (the big central theme that gets you started), and you start cutting the shape that you think you want it to be. But you find, if you do it right, that the wood has a grain of its own (characters develop and present new insights, concentrated thinking about the story opens new avenues). If you're sensible, you work with the grain and, if you come across a knot hole, you incorporate that into the design. This is not the same as 'making it up as you go along'; it's a very careful process of control.
Terry Pratchett